——
0.598 W/(m.K)
——
0.025 W/(m.K)
——
2.22 W/(m.K)
——
1.05 W/(m.K)
——
30 W/(m.K)
——
200 W/(m.K)
——
100 W/(m.K)
——
0.5 W/(m.K)
——
0.2 W/(m.K)
——
0.0166 W/(m.K)
——
1.31 W/(m.K)
——
1.5 W/(m.K)
——
110 W/(m.K)
——
1000 W/(m.K)
——
4000 W/(m.K)
——
0.3 W/(m.K)
——
0.2 W/(m.K)
——
0.024 W/(m.K)
——
0.25 W/(m.K)
——
1.3 W/(m.K)
——
116 W/(m.K)
——
140 W/(m.K)
——
18 W/(m.K)
——
20 W/(m.K)
——
50 W/(m.K)
——
53 W/(m.K)
——
126 W/(m.K)
——
6.5 W/(m.K)
——
394 W/(m.K)
——
40 W/(m.K)
——
113 W/(m.K)
——
40 W/(m.K)
——
8.68 W/(m.K)
——
0.12 W/(m.K)
——
0.2 W/(m.K)
——
0.042 W/(m.K)
——
0.5 W/(m.K)
——
3.2 W/(m.K)
——
22 W/(m.K)
——
150 W/(m.K)
——
18 W/(m.K)
——
24 W/(m.K)
——
50 W/(m.K)
——
15-30 W/(m.K)
——
70 W/(m.K)
——
10.2 W/(m.K)
——
120 W/(m.K)
——
59 W/(m.K)
——
50 W/(m.K)
——
7 W/(m.K)
——
0.04 W/(m.K)
——
0.2 W/(m.K)
——
0.5 W/(m.K)
——
0.034 W/(m.K)
——
0.3 W/(m.K)
——
3 W/(m.K)
——
6.7 W/(m.K)
——
190 W/(m.K)
——
41 W/(m.K)
——
19 W/(m.K)
——
26 W/(m.K)
——
36 W/(m.K)
——
70 W/(m.K)
——
14.8 W/(m.K)
——
75 W/(m.K)
——
115 W/(m.K)
——
23 W/(m.K)
——
0.15 W/(m.K)
——
0.2 W/(m.K)
——
0.2 W/(m.K)
——
0.75 W/(m.K)
——
0.017 W/(m.K)
——
0.03 W/(m.K)
——
0.01 W/(m.K)
——
300 W/(m.K)
——
320 W/(m.K)
——
250 W/(m.K)
——
18 W/(m.K)
——
41 W/(m.K)
——
40 W/(m.K)
——
170 W/(m.K)
——
12 W/(m.K)
——
21.2 W/(m.K)
——
40 W/(m.K)
——
16.5 W/(m.K)
——
0.17 W/(m.K)
——
0.12 W/(m.K)
——
0.16 W/(m.K)
——
0.13 W/(m.K)
——
0.024 W/(m.K)
Thermal Conductivity of Materials
The heat transfer characteristics of a solid material are measured by a property called thethermal conductivity, k (or λ), measured inW/m.K.It is a measure of a substance’s ability to transfer heat through a material byconduction.Note thatFourier’s lawapplies for all matter, regardless of its state (solid, liquid, or gas), therefore, it is also defined for liquids and gases.
Thethermal conductivityof most liquids and solids varies with temperature. For vapors, it also depends upon pressure. In general:
Most materials are very nearly homogeneous, therefore we can usually writek = k (T).Similar definitions are associated with thermal conductivities in the y- and z-directions (ky, kz), but for an isotropic material the thermal conductivity is independent of the direction of transfer, kx = ky = kz = k.
Thermal Conductivity of Metals
- the migration of free electrons
- lattice vibrational waves (phonons)
When electrons and phonons carry thermal energy leading to conduction heat transfer in a solid, the thermal conductivity may be expressed as:
k = ke+ kph
Metalsare solids and as such they possess crystalline structure where the ions (nuclei with their surrounding shells of core electrons) occupy translationally equivalent positions in the crystal lattice.Metalsin general havehigh electrical conductivity,high thermal conductivity, and high density. Accordingly, transport of thermal energy may be due to two effects:
- the migration offree electrons
- lattice vibrational waves (phonons).
When electrons and phonons carry thermal energy leading to conduction heat transfer in a solid, the thermal conductivity may be expressed as:
k = ke+ kph
The unique feature of metals as far as their structure is concerned is the presence of charge carriers, specificallyelectrons.The electrical and thermal conductivities of metalsoriginate fromthe fact that theirouter electrons are delocalized.Their contribution to the thermal conductivity is referred to as theelectronic thermal conductivity, ke.In fact, in pure metals such as gold, silver, copper, and aluminum, the heat current associated with the flow of electrons by far exceeds a small contribution due to the flow of phonons. In contrast, for alloys, the contribution of kphto k is no longer negligible.
Thermal Conductivity of Nonmetals
Fornonmetallic solids,kis determined primarily bykph, which increases as the frequency of interactions between the atoms and the lattice decreases. In fact, lattice thermal conduction is the dominant thermal conduction mechanism in nonmetals, if not the only one. In solids, atoms vibrate about their equilibrium positions (crystal lattice). The vibrations of atoms are not independent of each other, but are rather strongly coupled with neighboring atoms. The regularity of the lattice arrangement has an important effect onkph, with crystalline (well-ordered) materials likequartzhaving a higher thermal conductivity than amorphous materials like glass. At sufficiently high temperatures kph∝ 1/T.
Thequantaof the crystal vibrational field are referred to as ‘‘phonons.’’ A phonon is a collective excitation in a periodic, elastic arrangement of atoms or molecules in condensed matter, like solids and some liquids. Phonons play a major role in many of the physical properties of condensed matter, like thermal conductivity and electrical conductivity. In fact, for crystalline, nonmetallic solids such as diamond, kphcan be quite large, exceeding values of k associated with good conductors, such as aluminum. In particular, diamond has the highest hardness and thermal conductivity (k = 1000 W/m.K) of any bulk material.
Thermal Conductivity of Liquids and Gases
In physics, a fluid is a substance that continually deforms (flows) under an applied shear stress.Fluidsare a subset of the phases of matter and includeliquids,gases, plasmas and, to some extent, plastic solids. Because the intermolecular spacing is much larger and the motion of the molecules is more random for the fluid state than for the solid state,thermal energy transportis less effective. Thethermal conductivityof gases and liquids is therefore generally smaller than that of solids. In liquids, the thermal conduction is caused by atomic or molecular diffusion. In gases, the thermal conduction is caused by diffusion of molecules from higher energy level to the lower level.
Thermal Conductivity of Gases
The effect of temperature, pressure, and chemical species on thethermal conductivityof a gas may be explained in terms of thekinetic theory of gases.Air and other gases are generally good insulators, in the absence of convection. Therefore, many insulating materials (e.g.polystyrene) function simply by having a large number ofgas-filled pocketswhichprevent large-scale convection.交替的气体口袋和固体材料ses that the heat must be transferred through many interfaces causing rapid decrease in heat transfer coefficient.
Thethermal conductivity of gasesis directly proportional to the density of the gas, the mean molecular speed, and especially to themean free pathof molecule. The mean free path also depends on the diameter of the molecule, with larger molecules more likely to experience collisions than small molecules, which is the average distance traveled by an energy carrier (a molecule) before experiencing a collision. Light gases, such ashydrogenandheliumtypically havehigh thermal conductivity.Dense gases such as xenon and dichlorodifluoromethane have low thermal conductivity.
In general, the thermal conductivity of gases increases with increasing temperature.
Thermal Conductivity of Liquids
As was written, in liquids, the thermal conduction is caused by atomic or molecular diffusion, but physical mechanisms for explaining the thermal conductivity of liquids are not well understood. Liquids tend to have better thermal conductivity than gases, and the ability to flow makes a liquid suitable for removing excess heat from mechanical components. The heat can be removed by channeling the liquid through a heat exchanger. The coolants used in nuclear reactors include water or liquid metals, such as sodium or lead.
The thermal conductivity of nonmetallic liquids generally decreases with increasing temperature.